| 一氧化碳和甲烷在微波等离子体下直接转化成低碳烃(英文) |
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| 引用本文： | 陈栋梁,雷正兰,刘万楹,王真,洪品杰,戴树珊.一氧化碳和甲烷在微波等离子体下直接转化成低碳烃(英文)[J].天然气化学杂志,1998,7(1):80-84. |
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| 作者姓名： | 陈栋梁 雷正兰 刘万楹 王真 洪品杰 戴树珊 |
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| 作者单位： | 中国科学院成都有机化学研究所天然气化学实验室(陈栋梁，雷正兰，刘万楹)，云南大学化学系(王真，洪品杰，戴树珊) |
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| 摘 要： | 本文报道了微波等离子体下（２．４５ＧＨｚ）一氧化碳和甲烷直接转化成低碳烃的一种新方法。研究了影响产物分布的几个因素：微波输入功率、反应物比例及体系压力。乙炔和乙烷是主要有机产物。随着微波输入功率的增加和体系压力或ＣＨ４／ＣＯ比例的降低，乙炔含量增加，乙烷含量减少。反应中有少量乙烯和Ｃ３烃生成。没有检测到Ｃ４及含氧有机化合物。
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| 关 键 词： | 一氧化碳 甲烷 低碳烃 微波等离子体 |
DIRECT CONVERSION OF CARBON MONOXIDE AND METHANE TO LIGHT HYDROCARBONS BY MICROWAVE PLASMA |
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| Dongliang Chen,Zhenglan Lei,Wanying Liu,Zhen Wang,Pinjie Hong,Shushan Dai.DIRECT CONVERSION OF CARBON MONOXIDE AND METHANE TO LIGHT HYDROCARBONS BY MICROWAVE PLASMA[J].Journal of Natural Gas Chemistry,1998,7(1):80-84. |
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| Authors: | Dongliang Chen Zhenglan Lei Wanying Liu Zhen Wang Pinjie Hong Shushan Dai |
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| Institution: | Laboratory of Natural Gas Chemistry Chengdu Institute of Organic Chemistry, The Chinese Academy of Sciences Chengdu, Sichuan, 610041; Yunnan University |
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| Abstract: | A new method in which carbon monoxide and methane are directly converted to light hydrocarbons by microwave plasma (2.45 GHz) is reported. The factors affecting distribution of the products, e.g. microwave power, ratio of reactants, system pressure, were studied. Acetylene and ethane were the dominant organic products, and with microwave power increasing and system pressure or ratio of CH 4 to CO decreasing the content of acetylene increased, but ethane was contrary to it. A small amount of ethylene and C 3 hydrocarbons were also found, but C 4 hydrocarbons and oxygen containing organic compounds were not detected. |
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| Keywords: | carbon monoxide methane light hydrocarbons microwave plasma |
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