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Hydroformylation of methyl-3-pentenoate over a phosphite ligand modified Rh/SiO2 catalyst |
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| Authors: | Xianming Li Yunjie Ding Guiping Jiao Jingwei Li Li Yan Hejun Zhu |
| Institution: | aLaboratory of Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;bThe State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;cGraduate School of the Chinese Academy of Sciences, Beijing 100049, China |
| Abstract: | A phosphite ligand modified Rh/SiO2 catalyst has been developed for hydroformylation of internal olefins to linear aldehydes, which showed high activity and regioselectivity and could be separated easily by filtration after reaction in an autoclave. Effects of reaction temperature and syngas pressure on the performances of the catalyst in the reaction were also investigated. |
| Keywords: | Rh/SiO2 phosphite hydroformylation internal olefins linear aldehydes |
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