| CH_4在Mo/HZSM-5及其改性催化剂上的无氧芳构化(英文) |
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| 引用本文： | 张志刚,王承学,孙敬如.CH_4在Mo/HZSM-5及其改性催化剂上的无氧芳构化(英文)[J].天然气化学杂志,2000,9(4):326-330. |
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| 作者姓名： | 张志刚 王承学 孙敬如 |
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| 作者单位： | 吉林工学院化工系!吉林 长春 130012，吉林工学院化工系!吉林 长春 130012，吉林工学院化工系!吉林 长春 130012 |
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| 摘 要： | 运用微型固定床反应器装置，研究了Mo/HZSM-5催化剂的Mo载量、金属助剂改性、载体模数对甲烷无氧芳构化反应性能的影响。结果表明，Ni/Mo摩尔比为0.1的Mo-Ni/HZSM-5(SiO2/Al2O3=25)催化性能最好，其稳定性较好，芳烃收率最高可达15.74%；此时甲烷转化率60.24%，芳烃选择性26.13%。
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| 关 键 词： | 甲烷 芳构化 Mo/HZSM-5 改性 |
AROMATIZATION OF METHANE OVER Mo/HZSM-5 CATALYSTS AND MODIFIED Mo/HZSM-5 CATALYSTS UNDER NON-OXIDIZING CONDITIONS |
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| Zhigang Zhang,Chengxue Wang,Jingru Sun.AROMATIZATION OF METHANE OVER Mo/HZSM-5 CATALYSTS AND MODIFIED Mo/HZSM-5 CATALYSTS UNDER NON-OXIDIZING CONDITIONS[J].Journal of Natural Gas Chemistry,2000,9(4):326-330. |
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| Authors: | Zhigang Zhang Chengxue Wang Jingru Sun |
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| Institution: | Department of Chemical Engineering, Jilin Institute of Technology Changchun, Jilin 130012 |
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| Abstract: | The activities of Mo/HZSM-5 catalysts were examined in a fixed-bed flow microreactor. The influences of Mo loading, promoter and SiO2/Al2O3 ratio on the performance of the catalysts were investigated. It was found that Ni(0.1%)-Mo(3.5%)/HZSM-5 (SiO2/Al2O3=25) was the best catalyst, on which the maximum yield of aromatics was 15.7% with the conversion of methane of 60.2% and the selectivity to aromatics of 26.1%. |
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| Keywords: | methane aromatization modified Mo/HZSM-5 catalyst |
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