首页 | 本学科首页   官方微博 | 高级检索  
     检索      

Production of octyl levulinate biolubricant over modified H-ZSM-5: Optimization by response surface methodology
基金项目:This work was supported by CSIR-XII FYP Networking Project BLB.
摘    要:The present study highlighted the use of modified H-ZSM-5 (Meso-HZ-5) as heterogeneous catalyst for the synthesis of octyl levulinate biolubricant by catalytic esterification of biomass derived renewable levulinic acid (LA) with n-octanol. The process variables such as catalyst loading (X1), n-octanol to LA molar ratio (X2) and reaction temperature (X3) were optimized through response surface methodology (RSM), using Box-Behnken model. Analysis of variance was performed to determine the adequacy and significance of the quadratic model. The yield of octyl levulinate was obtained to be 99% at optimum process parameters. The developed quadratic model was found to be adequate and statistically accurate with correlation value (R2) of 0.9971 to predict the yield of octyl levulinate biolubricant. The study was also extended on the validation of theoretical and experimental data, including catalyst reusability.

关 键 词:H-ZSM-5  乙酰丙酸  响应面法  优化  非均相催化剂  修改  生产  最佳工艺参数
本文献已被 CNKI 维普 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号