| Thermodynamic and Equilibrium Composition of Using Iron Oxide as an Oxygen Carrier Nonflame Combustion Technology Analysis in |
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| 作者姓名： | 辛嘉余 王华 何方 张智民 |
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| 作者单位： | Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming 650093, China |
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| 基金项目： | Supported by the National Natural Science Foundation of China （No. 50574046, No. 50164002,） and Science ＆ Technology Foundation of Baoshan Iron and Steel Co. Ltd, Natural Science Foundation of Yunnan province （No. 2004E0012Q）, High School Doctoral Subject Special Science and Research Foundation of Ministry of Education （N0. 20040674005）. |
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| 摘 要： | 本文介绍了一种新的燃烧体系--熔融盐循环热载体无烟燃烧技术。这种燃烧体系杜绝环境污染气体NOx和CO2的排放，可以实现真正零排放的目标。计算了以Fe2O3作为氧载体的无烟燃烧体系的热力学参数。用最小吉布斯自由能原则，分析了Fe2O3与CH4的平衡组成。分析表明，如果要想在产物中产生高纯度的CH4完全氧化产物CO2和H2O，Fe2O3与CH4必须达到高摩尔比，如果Fe2O3的量不足，就会产生较多的部分氧化产物如CO，H2甚至C
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| 关 键 词： | 氧化铁 热动力学分析 阻燃技术 热循环载体 熔盐 平衡组成 |
| 收稿时间： | 2005-11-09 |
| 修稿时间： | 2005-12-20 |
Thermodynamic and Equilibrium Composition Analysis of Using Iron Oxide as an Oxygen Carrier in Nonf lame Combustion Technology |
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| Jiayu;Xin;Hua;Wang;Fang;He;Zhimin;Zhang.Thermodynamic and Equilibrium Composition of Using Iron Oxide as an Oxygen Carrier Nonflame Combustion Technology Analysis in[J].Journal of Natural Gas Chemistry,2005,14(4):248-253. |
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| Authors: | Jiayu;Xin;Hua;Wang;Fang;He;Zhimin;Zhang |
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| Abstract: | |
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| Keywords: | nonflame combustion technology thermal cyclic carrier molten salt equilibrium composition thermodynamic analysis |
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