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Dispersing SnO2 nanocrystals in amorphous carbon as a cyclic durable anode material for lithium ion batteries
Authors:Renzong Hu Wei Sun Meiqin Zeng Min Zhu
Institution:School of Materials Science and Engineering, South China University of Technology, Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, Guangzhou 510640, Guangdong, China
Abstract:We demonstrate a facile route for the massive production of SnCb/carbon nanocomposite used as high-capacity anode materials of nextgeneration lithium-ion batteries.The nanocomposite had a unique structure of ultrafine SnO_2 nanocrystals(~5 nm,80 wt%) homogeneously dispersed in amorphous carbon matrix.This structure design can well accommodate the volume change of Li~+ insertion/desertion in SnO_2,and prevent the aggregation of the nanosized active materials during cycling,leading to superior cycle performance with stable reversible capacity of 400 mAh/g at a high current rate of 3.3 A/g.
Keywords:lithium ion battery  anode  SnO2 nanocrystals  amorphous carbon  facile strategy
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