Organometallic complexes containing thiosemicarbazone and related ligands. Part II(1). η3-allyl dicarbonyl complexes of molybdenum(II) with attached thiosemicarbazone ligands |
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| Authors: | Michel J M Campbell Elizabeth Morrison Vernon Rogers Paul K Baker |
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| Institution: | (1) The School of Chemistry, Thames Polytechnic, Wellington Street, SE18 6PF London, UK;(2) The Department of Chemistry, University College of North Wales, LL57 2UW Bangor, UK |
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| Abstract: | Summary The  -allylmolybdenum(II) complexes MoX(CO)2-(NCMe)2( 3-C3H4R)] (X=Cl, Br and I; R=H and 2-Me) react either in dichloromethane or acetonitrile with thiosemicarbazones to give the new complexes MoX-(CO)2(R R CNNHCSNH2)(3-C3H4R)] (R=H or Me; R'=Me, Et, Pr or Ph)via displacement of acetonitrile ligands. |
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