Kinetics and mechanism of oxidation of 1,4-butanediol by chromium(VI) in acid perchlorate medium |
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| Authors: | Chetna Gupta Som K Mishra Prem D Sharma |
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| Institution: | (1) Department of Chemistry, University of Rajasthan, 302004 Jaipur, India |
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| Abstract: | Summary The kinetics of oxidation of 1,4-butanediol by chromium(VI) was studied in acid perchlorate medium and the oxidation product of the diol was identified as 4-hydroxybutanal. The kinetic rate law observed accounted for the complex dependence of the hydrogen ion k=(k2K1H+]+k3K1K2H+]2)/(1+K1H]+) where k is the observed second-order rate constant. |
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