Near infrared thieno[3,4-b]pyrazine sensitizers for efficient quasi-solid-state dye-sensitized solar cells |
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Authors: | Lu Xuefeng Zhou Gang Wang Hong Feng Quanyou Wang Zhong-Sheng |
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Institution: | Department of Chemistry & Laboratory of Advanced Materials, Fudan University, 2205 Songhu Road, Shanghai 200438, P. R. China. |
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Abstract: | Three near infrared (NIR) metal-free organic sensitizers (FNE32, FNE34, FNE36) based on the thieno3,4-b]pyrazine derivative have been designed and synthesized for application in quasi-solid-state dye-sensitized solar cells (DSSCs). These organic dyes demonstrate maximum absorption bands at 596-625 nm due to the presence of the thieno3,4-b]pyrazine derivative, which facilitates the intramolecular electron transfer from the donor to the acceptor. Quasi-solid-state DSSCs based on FNE34 display efficient photoelectric conversion over the whole visible range extending into the NIR region up to 900 nm with maximum incident monochromatic photon-to-electron conversion efficiency (IPCE) of 77%, yielding a short-circuit photocurrent density of 16.24 mA cm(-2) and a power conversion efficiency of 5.30%. To the best of our knowledge, this is the highest efficiency for quasi-solid-state DSSCs based on an organic NIR dye. When exposed to one-sun illumination for 1000 h, the quasi-solid-state DSSC based on FNE34 exhibits good long-term stability with almost constant power conversion efficiency. |
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