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Synthesis and study of the fluorescent behavior of 3-pyridinecarbonitriles
Authors:Madhukar N Jachak  Sandeep M Bagul  Bhausaheb K Ghotekar  Raghunath B Toche
Institution:(1) Organic Chemistry Research Center, Department of Chemistry, K.T.H.M. College, Gangapur Road, Nashik, 422 002, Maharashtra, India
Abstract:Abstract  A series of (2E)-3-(1-chloro-6-methoxy-3,4-dihydronaphthalen-2-yl)-1-(4-aryl)prop-2-en-1-ones (chalcones) have been synthesized by a new synthetic route. The 3-pyridinecarbonitrile derivatives were synthesized by the Michael reaction of malononitrile (in base) and aroylacetonitriles (in acid) with chalcones in one pot. The fluorescent properties and quantum yields of these compounds were studied. Graphical Abstract   MediaObjects/706_2009_116_Figa_HTML.gif
Keywords:Chalcone  3-Pyridinecarbonitriles  Fluorescence  Wittig reaction  Grignard reaction
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