Fluordiazadiphosphetidine, 16. Mitt. |
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| Authors: | Kurt Utvary Manfred Kubjacek |
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| Institution: | (1) Institut für Anorganische Chemie, Technische Universität Wien, A-1060 Wien, Österreich |
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| Abstract: | The reaction of (CH3NPF3)2 with NH3 and primary aliphatic and aromatic amines in the molar ratio 3:2 yields (CH4NPF4)2 and the monoamino substituted fluordiaza-diphosphetidines. These react with N-Trimethylsilyl-methylamine to the mixed diamino substituted compounds.With 1,4-Diazabicyclo2.2.2]octan as HF-acceptor a second step of nucleophilic substitution with NH3 and primary amines is possible. In the case of ammonia a by- product has been identified as the 1:1 adduct of (CH3NPF2NH2)2 with 1,4-diazabicyclo2.2.2]octan.Herrn Prof. Dr.O. Hromatka zum 80. Geburtstag gewidmet. |
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| Keywords: | Aza Cyclic (non-carbon) Heterocyclic (N P) Phospha |
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