Alkoholyse aromatischer Carbonsäureester |
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| Authors: | Sylvia Gödl Bernd Trathnigg Hans Junek |
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| Institution: | (1) Institut für Organische Chemie, Universität Graz, A-8010 Graz, Österreich |
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| Abstract: | The alcoholysis of various esters of aromatic carboxylic esters with octadecanol in the presence of lead stearate was investigated by chromatographic analysis of the reaction mixtures. The reactivity of the esters was found to be strongly affected by the substitution pattern of the aromatic nucleus as well as by the structure of the alkoxy group. Electron donating substituents in a suitable position lead to a remarkable increase in reactivity compared to the unsubstituted alkyl esters.Herrn Prof. Dr.K. Schlögl zum 60. Geburtstag gewidmet. |
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| Keywords: | Mono and polycarboxylic esters Metal salt catalysis Kinetics Chromatographic analysis |
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