Enantioselective synthesis of 1-arylethanediols by rhodium-catalyzed transfer hydrogenation of α-tosyloxyarylketones期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Enantioselective synthesis of 1-arylethanediols by rhodium-catalyzed transfer hydrogenation of α-tosyloxyarylketones

Authors:	Do-Min Lee Gullapalli Kumaraswamy and Kee-In Lee

Institution:	(1) Bio-Organic Science Division, Korea Research Institute of Chemical Technology, P?O. Box 107, Yusong, Taejon, 305-600, South Korea;(2) Organic Division III, Indian Institute of Chemical Technology, Hyderabad, 500 007, India;

Abstract:	Abstract Catalytic transfer hydrogenation of α-tosyloxyarylketones mediated by a chiral rhodium complex using an azeotropic mixture of formic acid/triethylamine afforded the corresponding 1-arylethanediol monotosylates in excellent yield with high enantioselectivity.

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