Metal-free and metallo-porphyrazines with eight [5-thiopentyl 2-methoxy-4,6-bis (trifluoromethyl) benzoate] substituent |
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Authors: | Ergün Gonca |
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Institution: | 1. ?anakkale Onsekiz Mart University, Terzioglu Campus, Faculty of Engineering, Department of Chemical Engineering, ?anakkale, Turkeyegonca@gmail.com ergonca@hotmail.com |
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Abstract: | The reaction of (5-hydroxypentylthio magnesium porphyrazine) with 2-methoxy-4,6-bis(trifluoromethyl)benzoic acid in DCCI and PTSA, esterified MgPz having 5-thiopentyl 2-methoxy-4,6-bis(trifluoromethyl)benzoate] substituent was obtained. Further reactions of the metal-free porphyrazine with M2+(Mg, Co, Cu, Zn, Fe) acetates have produced the metallo-porphyrazines. Finally, by the reaction of FePzCl with pyridine or pyrazine compounds, FePz(py)2] and FePz(pyz)]n complexes were prepared as the novel stable complexes, respectively. The target compounds have been characterized by using different spectroscopic methods such as FT-IR, UV-Vis, mass, 1H, 13C, and 19F NMR together with elemental analysis. The aggregation and the solubility features were indicated in various concentrations and solvents. |
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Keywords: | Porphyrazine 2-methoxy-4 6-bis(trifluoromethyl)benzoic acid esterification bisaxial complex bridged complex |
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