Syntheses of Optically Active Polyacrylates |
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| Authors: | V D ATHAWALE S R GAONKAR |
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| Institution: | Department of Chemistry , University of Mumbai , Vidyanagari, Mumbai, 400 098, India |
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| Abstract: | ABSTRACT Different secondary alcohols were resolved by lipase catalyzed transesterification using 2,3-butanedione monoxime acrylate as acrylating agent. The results showed that the reaction rates were the fastest among reactions reported until now. The effect of solvent on the transesterification rate was studied. The enantiomeric excess (ee) and enantiomeric purity (E value) of all the acrylate monomers were determined. The synthesized optically active acrylate monomers were polymerized by free radical polymerization technique. |
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| Keywords: | Lipase Acrylate Transesterification Resolution Optically Active |
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