Synthesis and Properties of New Thiacalixarene Derivatives with Palladium Ion |
| |
| Authors: | Zhi-Feng Ye Zhi-Gang Pan Wei-Jiang He Xian-Fa Shi Long-Gen Zhu |
| |
| Institution: | (1) State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China;(2) Chemistry Department, Tongji University, Shanghai, 200092, P. R. China |
| |
| Abstract: | Three new thiacalix4]arene derivatives, 5,11,17,23-tetra-tert-butyl-25,27-di(2-hydroxyethoxy)-26,28-dihydroxythiacalix-{}4]arene (2), 5,11,17,23-tetra-tert-25, 26,27,28-tetrakis(methylcarboxyl)methoxy]thiacalix4]arene (3),5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis(2-hydroxy-1-propanoxy)thiacalix4]arene (4), were synthesized for the first time. The coordination properties of thiacalix4]arene(1) and its derivatives (2 and 4) were investigated by detecting the interactions betweenthese compounds and two palladium complexes, cis-Pd(en)(H2O)2]2+ and cis-Pd(dtco-3-OH)(H2O)2]2+, by means of electrospray ionization mass spectrometry (ESI-MS) technique. |
| |
| Keywords: | electrospray mass spectrometry palladium ion thiacalix[4]arene |
| 本文献已被 SpringerLink 等数据库收录！ |
|
