N-(4-amino-7-nitrobenzaoxa-1,3-diazole)-substituted aza crown ethers: complexation with alkali, alkaline earth metal ions and ammonium |
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| Authors: | Nelly N Mateeva Shihab D Deiab Edikan E Archibong Mercedes Jackson Bereket Mochona Madhavi Gangapuram Kinfe K Redda |
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| Institution: | 1. Department of Chemistry, Florida A&M University, 1530 M.L.King, Jr. Blvd, 219 Jones Hall, Tallahassee, FL, 32307, USA
2. College of Pharmacy and Pharmaceutical Sciences, Florida A&M University, Tallahassee, FL, 32307, USA
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| Abstract: | Three novel aza-crown ether derivatives incorporating 4-amino-7-nitrobenzaoxa-1,3-diazole (NBD) chromophore were synthesized and their structure confirmed by 1H-NMR, IR and elemental analysis. The influence of the solvent polarity and protonation on the photophysical properties of NBD-15-crown-5 was studied by UV/Vis and fluorescence methods. The influence of the investigated cations on the absorption spectra of the ligands was negligible, however emission was strongly affected. Complexation and binding stability of NBD-aza-15-crown-5 and NBD-aza-18-crown-6 were studied using fluorescence spectroscopy. NBD-aza-18-crown-6 exhibits strong selectivity toward Ca2+ and Sr2+ ions with formation constants about 103 times higher than the formation constants with the other ions included in the study. |
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