| 长度可控杆状SBA-15的合成 |
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| 引用本文： | 王敏,李冬,蔡文京,姜男哲.长度可控杆状SBA-15的合成[J].高等学校化学学报,2014,35(1):26. |
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| 作者姓名： | 王敏 李冬 蔡文京 姜男哲 |
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| 作者单位： | 延边大学工学院化工系, 延吉 133002 |
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| 基金项目： | 国家自然科学基金(批准号:21263026);吉林省教育厅“十二五”科学技术研究项目(批准号:2012-7)资助~~ |
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| 摘 要： | 以三嵌段共聚物P123为结构导向剂, 天然高聚物壳聚糖为添加剂, 合成出分散性较好的杆状结构SBA-15. 通过调节体系中壳聚糖的含量, 可以实现对产物形貌的控制, 即从颗粒到短杆状, 最后到长杆状. 壳聚糖的加入不仅使SBA-15的介孔结构更加长程有序, 同时也提高了其比表面积和孔容, 其最高值分别达到1157 m2/g和1.53 cm3/g.
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| 关 键 词： | SBA-15 形貌控制 壳聚糖 |
| 收稿时间： | 2013-08-23 |
Synthesis of Length Controllable Ordered Mesoporous Rodslike SBA-15 by Co-surfactant Method† |
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| WANG Min,LI Dong,CAI Wenjing,JIANG Nanzhe.Synthesis of Length Controllable Ordered Mesoporous Rodslike SBA-15 by Co-surfactant Method†[J].Chemical Research In Chinese Universities,2014,35(1):26. |
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| Authors: | WANG Min LI Dong CAI Wenjing JIANG Nanzhe |
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| Institution: | Department of Chemical Engineering and Technology, College of Engineering, Yanbian University, Yanji 133002, China |
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| Abstract: | SBA-15 rods with different lengths(from hexagonal paticials to short rods, and to longer rods) were synthesized via triblock copolymer P123 as a structure-directing agent and chitosan as a co-surfactant. The results show that chitosan is indispensable for tuning the length of SBA-15 rods. Addition of chitosan could improve the periodicity of the SBA-15 and the specific surface area and total proe volume are increased to 1157 cm2/g and 1.53 cm3/g, respectively. |
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| Keywords: | SBA-15 Morphology control Chitosan |
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