| 三氯化钕异丙醇络合物的晶体结构和分子结构 |
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| 引用本文： | 金钟声,王生龙,王佛松,申成,杨光第,樊玉国.三氯化钕异丙醇络合物的晶体结构和分子结构[J].高等学校化学学报,1985,6(8):735. |
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| 作者姓名： | 金钟声 王生龙 王佛松 申成 杨光第 樊玉国 |
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| 作者单位： | 1. 中国科学院长春应用化学研究所;
2. 吉林大学理论化学研究所 |
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| 摘 要： | 本文报导了X射线衍射法确定的三氯化钕异丙醇络合物NdCl3·(CH3CHOHCH3)3]2的晶体结构。在晶体中每二个钕离子通过二个氯离子形成的氯桥相联,组成一个双核稀土络合物分子。其中每个Nd离子是七配位的。
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| 收稿时间： | 1984-03-16 |
The Crystal and Molecular Structure of Neodymium Chloride Isopropyl Alcohol Complex |
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| Jin Zbongsheng,Wang Shenglong,Wang Fusong,Shen Cheng,Yang Guangdi,Fan Yuguo.The Crystal and Molecular Structure of Neodymium Chloride Isopropyl Alcohol Complex[J].Chemical Research In Chinese Universities,1985,6(8):735. |
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| Authors: | Jin Zbongsheng Wang Shenglong Wang Fusong Shen Cheng Yang Guangdi Fan Yuguo |
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| Institution: | 1. Changchun Institute of Applied Chemistry, Academic Sinica;
2. Institute of Theoretical Chemistry of Jilin University, Changchun |
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| Abstract: | The crystal structure of NdCl5·(CH5CHOHCH3)]2 has been determined by X-ray diffraction method. It is triclinic and the space group is P1, with dimensions: a= 11.184(2)Å, b= 13.462(3)Å,c = 5.9794(9)Å, α = 101.37(2) °β = 93.6l(2)°,γ= 69.46(2)°. The structure was solved by patterson method. The final residual factor is R= 0.038. The feature of the crystal structure is that every two Nd ions are linked in pairs through a chlorine bridge o?two chlorine ions to form a complex molecule and every Nd ion is seven-coordinate. |
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