| 高密度烃燃料四环[9.2.1.02,10.13,8]十四烷的合成及热裂解 |
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| 引用本文： | 杜咏梅,王伟,亢建平,李春迎,杨建明,张伟,吕剑.高密度烃燃料四环[9.2.1.02,10.13,8]十四烷的合成及热裂解[J].高等学校化学学报,2011,32(8):1849-1853. |
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| 作者姓名： | 杜咏梅 王伟 亢建平 李春迎 杨建明 张伟 吕剑 |
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| 作者单位： | 西安近代化学研究所,西安,710065 |
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| 基金项目： | 国防科工委基础产品创新计划火炸药科研专项(批准号:A0920061370)资助 |
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| 摘 要： | 以双环戊二烯和茚为原料,经D-A反应及催化加氢合成高密度烃燃料四环9.2.1.02,10.13.8]十四烷(TDTD).采用裂解器及色质联用进行了四环9.2.1.02.10.1 3.8]十四烷的热裂解研究,考察了不同温度及时间对热裂解转化率的影响,结果显示,温度对转化率影响较大.分析裂解产物,推测了裂解机理,以裂解...
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| 关 键 词： | 高密度烃燃料 四环[9.2.1.02.10.13 8]十四烷 热裂解 |
| 收稿时间： | 2010-09-19 |
Synthesis and Thermal Decomposition of Tetracyclo[9.2.1.0~(2,10).1~(3,8)] Tetradecane as a High Density Hydrocarbon Fuel |
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| DU Yong-Mei,WANG Wei,KANG Jian-Ping,LI Chun-Ying,YANG Jian-Ming,ZHANG Wei,L Jian.Synthesis and Thermal Decomposition of Tetracyclo[9.2.1.0~(2,10).1~(3,8)] Tetradecane as a High Density Hydrocarbon Fuel[J].Chemical Research In Chinese Universities,2011,32(8):1849-1853. |
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| Authors: | DU Yong-Mei WANG Wei KANG Jian-Ping LI Chun-Ying YANG Jian-Ming ZHANG Wei L Jian |
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| Institution: | DU Yong-Mei,WANG Wei,KANG Jian-Ping,LI Chun-Ying,YANG Jian-Ming,ZHANG Wei,L(U) Jian |
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| Abstract: | As a high density hydrocarbon fuel,tetracyclo9.2.1.02,10.13,8]tetradecane was synthesized from dicyclopentadiene and indene by D-A reaction and hydrogenation.Thermal decomposition of tetracyclo9.2.1.02,10.13,8]tetradecane was studied in a decomposition reactor,and the products were detected by gas chromatography-mass spectroscopy.The conversion of tetracyclo9.2.1.02,10.13,8]tetradecane at different temperature and time was investigated.The results indicated that the effect of temperature was superior to ... |
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| Keywords: | High density hydrocarbon fuel Tetracyclo[9 2 1 02 10 13 8]tetradecane Thermal decomposition |
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