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| 二维层状磷酸亚磷酸钒(Ⅳ)化合物[V2O2(OH)(HPO3)(HPO3)0.7(PO3OH)0.3].(C6N2H16)0.5的水热合成与结构表征 | |
| 引用本文： | 付文升,李光华,王莉,梁国明,孙宇阳,冯守华. 二维层状磷酸亚磷酸钒(Ⅳ)化合物[V2O2(OH)(HPO3)(HPO3)0.7(PO3OH)0.3].(C6N2H16)0.5的水热合成与结构表征[J]. 高等学校化学学报, 2005, 26(9): 1607-1609 |
| 作者姓名： | 付文升 李光华 王莉 梁国明 孙宇阳 冯守华 |
| 作者单位： | 1. 重庆师范大学化学学院,重庆,400047;吉林大学化学学院,无机合成与制备化学国家重点实验室,长春,130023 2. 吉林大学化学学院,无机合成与制备化学国家重点实验室,长春,130023 3. 重庆师范大学化学学院,重庆,400047 |
| 摘 要： | 迄今, 在中温水热条件下已合成了大量具有空旷骨架结构的过渡金属磷酸盐微孔材料[1], 这类材料在非线性光学材料、磁性材料、超导材料及催化等诸多方面具有潜在的应用前景[2～5]. |
| 关 键 词： | 磷酸亚磷酸钒 水热合成 结构 有机模板剂 |
| 文章编号： | 0251-0790(2005)09-1607-03 |
| 收稿时间： | 2005-01-11 |
| 修稿时间： | 2005-01-11 |
Hydrothermal Synthesis and Characterization of a Vanadium(Ⅳ) Phosphate Phosphite with Two-dimensional Layered Structures:[V2O2(OH)(HPO3)(HPO3)0.7(PO3OH)0.3](C6N2H16)0.5 |
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| FU Wen-Sheng,LI Guang-Hua,WANG Li,LIANG Guo-Ming,SUN Yu-Yang,FENG Shou-Hua. Hydrothermal Synthesis and Characterization of a Vanadium(Ⅳ) Phosphate Phosphite with Two-dimensional Layered Structures:[V2O2(OH)(HPO3)(HPO3)0.7(PO3OH)0.3](C6N2H16)0.5[J]. Chemical Research In Chinese Universities, 2005, 26(9): 1607-1609 | |
| Authors: | FU Wen-Sheng LI Guang-Hua WANG Li LIANG Guo-Ming SUN Yu-Yang FENG Shou-Hua |
| Affiliation: | 1. College of Chemistry, Chongqing Normal University, Chongqing 400047, China; 2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China |
| Abstract: | An organically templated vanadium phosphate phosphite, [V2O2(OH)(HPO3)(HPO3)0.75(PO3OH)0.3](C6N2H16)0.5 (1), was hydrothermally synthesized and characterized by single crystal X-ray diffraction. Compound 1 crystallizes in monoclinic system, space group C2/c with cell parameters a=1.305 58(18) nm, b=1.020 69(10) nm, c=1.909 8(2) nm, V=2544.9(5) nm3 and Z=8. It possesses a layered architecture and organic template molecules located between the inorganic layers forming hydrogen bonds. The inorganic layers are constructed of V(Ⅳ)O5 square pyramid, [PO3OH2-] pyramid and [HPO2-3] pseudo pyramid by sharing vertices. |
| Keywords: | Vanadium phosphate phosphite Hydrothermal synthesis Structure Organic template |
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