| 含苯乙炔的可自交联高温高性能聚芳醚酮的合成与性能 |
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| 引用本文： | 马晓野,关绍巍,陈春海,王贵宾,姜振华.含苯乙炔的可自交联高温高性能聚芳醚酮的合成与性能[J].高等学校化学学报,2007,28(3):600-602. |
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| 作者姓名： | 马晓野 关绍巍 陈春海 王贵宾 姜振华 |
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| 作者单位： | 吉林大学麦克德尔米德实验室,长春,130012 |
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| 摘 要： | 将可交联的苯乙炔结构引入到热塑性聚芳醚酮链中, 并对其交联前后的性能进行了深入研究.
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| 关 键 词： | 聚芳醚酮 苯乙炔 交联 |
| 文章编号： | 0251-0790（2007）03-0600-03 |
| 收稿时间： | 2006-10-16 |
| 修稿时间： | 2006-10-16 |
Synthesis and Properties of a Novel Crosslinkable Poly(aryl ether ketone) Containing Pendent Phenylethynyl Moieties |
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| MA Xiao-Ye,GUAN Shao-Wei,CHEN Chun-Hai,WANG Gui-Bin,JIANG Zhen-Hua.Synthesis and Properties of a Novel Crosslinkable Poly(aryl ether ketone) Containing Pendent Phenylethynyl Moieties[J].Chemical Research In Chinese Universities,2007,28(3):600-602. |
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| Authors: | MA Xiao-Ye GUAN Shao-Wei CHEN Chun-Hai WANG Gui-Bin JIANG Zhen-Hua |
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| Institution: | Alan G. Macdiarmid Institute, Jilin University, Changchun 130012, China |
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| Abstract: | A type of novel crosslinkable poly(aryl ether ketone)s containing pendent phenylethynyl moieties(PEP-PAEK-Fn) were synthesized. The polymers were prepared by copolycondensation reaction of difluoro-monomer with potassium salt of 4-phenylethynylphenyl hydroquinone(PEP-PH) and 4,4'-isopropylidenediphenol(BPA). The Mns and Mw/Mns of polymers determined by GPC with polystyrene standard were 46700, 100000 and 1.6, respectively. The resulting polymers were thermally crosslinked at 370 ℃ for 2 h in N2 atmosphere. The glass transition temperature is increased after crosslinking. The cured polymers show a good chemical resistance and high thermal stability up to 500 ℃ under nitrogen. |
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| Keywords: | Poly(aryl ether ketone) Diphenyl ethynel Crosslinking |
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