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室温下激发强度对ZnO晶须发光的影响
引用本文:郭星原,丁战辉,赵旭东,邱利霞,薛燕峰,许大鹏.室温下激发强度对ZnO晶须发光的影响[J].高等学校化学学报,2010,31(2):243-246.
作者姓名:郭星原  丁战辉  赵旭东  邱利霞  薛燕峰  许大鹏
作者单位:1. 吉林大学物理学院,长春,130021
2. 吉林大学物理学院,长春,130021;吉林大学无机合成与制备化学国家重点实验室,长春,130012
3. 吉林大学无机合成与制备化学国家重点实验室,长春,130012
基金项目:中央高校基本科研业务费专项资金(批准号:20871052)资助
摘    要:采用浮区法(FZ)在高氧压条件下生长出大尺寸的ZnO单晶晶须.X射线衍射(XRD)和拉曼光谱(Raman)分析结果表明,生长的ZnO单晶晶须为六方结构晶体,沿(100)晶面方向有明显的择优生长取向.研究了0.3 MPa氧压下生长的ZnO晶须的变功率光致发光光谱,结果表明,晶须在室温下有比较高的紫外光致发光效率和较低的缺陷,其紫外发光激发强度的阈值1 kW/cm2.

关 键 词:氧化锌  晶须  X射线衍射  拉曼光谱  光致发光
收稿时间:2009-03-23

Influence of Excitation Intensities on Photoluminescence of ZnO(Wurtzite) Whiskersat Room Temperature
GUO Xing-Yuan,DING Zhan-Hui,ZHAO Xu-Dong,QIU Li-Xia,XUE Yan-Feng,XU Da-Peng.Influence of Excitation Intensities on Photoluminescence of ZnO(Wurtzite) Whiskersat Room Temperature[J].Chemical Research In Chinese Universities,2010,31(2):243-246.
Authors:GUO Xing-Yuan  DING Zhan-Hui    ZHAO Xu-Dong  QIU Li-Xia  XUE Yan-Feng  XU Da-Peng
Institution:1.College of Physics;Jilin University;Changchun 130021;China;2.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry;Changchun 130012;China
Abstract:ZnO(wurtzite) whiskers were grown with a floating zone method using ZnO powder as starting materials under 0.3 MPa oxygen pressures. The as-grown samples were characterized by X-ray diffraction and Raman scattering, and their characteristic peaks verify that the as-grown ZnO whiskers have excellent hexagonal wurtzite phase and (100) orientation. The photoluminescence properties of the as-grown ZnO whiskers were measured under 266 nm-light excitation from a Nd∶YAG laser, and the influence of various laser intensity on the photoluminescence of the ZnO whiskers was investigated. It was found that the threshold of UV was higher than 1 kW/cm2.
Keywords:ZnO  Whisker  X-ray diffraction  Raman spectrum  Photoluminescence  
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