| 杂多酸催化甲苯磺化合成4,4’-二甲二苯砜的研究 |
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| 引用本文： | 吴通好,李永国,杨洪茂,王国甲,华士英,姜玉子,于剑锋.杂多酸催化甲苯磺化合成4,4’-二甲二苯砜的研究[J].高等学校化学学报,1992(5). |
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| 作者姓名： | 吴通好 李永国 杨洪茂 王国甲 华士英 姜玉子 于剑锋 |
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| 作者单位： | 吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系，吉林大学化学系 长春 130021，长春 130021，长春 130021，长春 130021，长春 130021，长春 130021，长春 130021 |
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| 摘 要： | 通过实验证实杂多酸对甲苯磺化合成4,4’-二甲二苯砜反应具有较好的催化活性,利用紫外光谱研究了杂多酸与对甲苯磺酸的作用。
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| 关 键 词： | 杂多酸 甲苯 磺化 4 4′-二甲二苯砜 |
Studies on HPA Catalysis for the Reaction of Toluene Sulfonation to 4,4' -Dimethyl diphenylsulfone |
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| WU Tong-hao,LI Yong-guo,YANG Hong-mao,WANG Guo-jiaHUA Shi-ying,JIANG Yu-zi,YU Jian-feng.Studies on HPA Catalysis for the Reaction of Toluene Sulfonation to 4,4'''' -Dimethyl diphenylsulfone[J].Chemical Research In Chinese Universities,1992(5). |
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| Authors: | WU Tong-hao LI Yong-guo YANG Hong-mao WANG Guo-jiaHUA Shi-ying JIANG Yu-zi YU Jian-feng |
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| Abstract: | It is proved by the experiment that HPA is a good catalyst for the reaction of toluene sulfonation to 4,4'-dimethyldiphenyl sulfone. The effect of HPA on p-methyl sulfonic acid has been studied by means of UV and variable-temperature 1H NMR. The preliminary catalytic mechnism is also proposed. |
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| Keywords: | Heteropoly acid Toluene Sulfonation 4 4'-Dimethyldiphenyl sulfone |
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