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温控相转移催化--水/有机两相催化新进展
引用本文:金子林,梅建庭,蒋景阳.温控相转移催化--水/有机两相催化新进展[J].高等学校化学学报,2000,21(6):941-946.
作者姓名:金子林  梅建庭  蒋景阳
作者单位:大连理工大学精细化工国家重点实验室,大连,116012
基金项目:中国科学院资助项目,中国石化集团公司资助项目,29792074,,,
摘    要:综述了“温控相转移催化”的原理,温控膦配体的设计、合成及其在水溶性极小的底物高碳烯烃的水/有机两相氢甲酰化反应中的应用效果。

关 键 词:水溶性膦配体  温控相转移催化  水/有机两相催化

Thermoregulated Phase-transfer Catalysis--Recent Advances in Water/Organic Biphasic Catalysis
JIN Zi-Lin,MEI Jian-Ting,JIANG Jing-Yang.Thermoregulated Phase-transfer Catalysis--Recent Advances in Water/Organic Biphasic Catalysis[J].Chemical Research In Chinese Universities,2000,21(6):941-946.
Authors:JIN Zi-Lin  MEI Jian-Ting  JIANG Jing-Yang
Abstract:Water/organic biphasic catalysis provided a kind effective way for solving the problem of difficulty from recovering the catalyst in homogeneous catalysis theoretically and practically. So far its application range has been seriously restricted by the water solubility of the substrates. Such a restriction will be fundamentally eliminated by thermoregulated phase transfer catalysis. The principle of the thermoregulated phase transfer catalysis, the design and synthesis of thermoregulated phase transfer ligands and their application in the water/organic two phase hydroformylation of higher olefins severally insoluble in water, were systematically introduced.
Keywords:Water  soluble phosphiino ligands  Thermoregulated phase  transfer catalysis  Water/organic two  phase hydroformylation  Homogeneous catalysts separation  
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