| 铁－芳烃络合物光引发剂的吸收光谱研究 |
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| 引用本文： | 陈旭东,黄新华,陈用烈,梁兆熙.铁－芳烃络合物光引发剂的吸收光谱研究[J].高等学校化学学报,1994(4). |
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| 作者姓名： | 陈旭东 黄新华 陈用烈 梁兆熙 |
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| 作者单位： | 西南师范大学化学系，中山大学高分子研究所 |
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| 摘 要： | 铁－芳烃络合物光引发剂的吸收光谱研究陈旭东，黄新华陈用烈，梁兆熙（西南师范大学化学系重庆，６３０７１５）（中山大学高分子研究所广州）关键词铁－芳烃络合物，光引发剂，吸收光谱，光解铁－芳烃络合物作为环氧化物阳离子聚合光引发剂已引起人们关注［１，２］．我...
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| 关 键 词： | 铁－芳烃络合物，光引发剂，吸收光谱，光解 |
Study of Adsorption Spectroscopy on Iron-Arene Complex Photoinitiator |
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| CHEN Xu-Dong, HUANG Xin-Hua.Study of Adsorption Spectroscopy on Iron-Arene Complex Photoinitiator[J].Chemical Research In Chinese Universities,1994(4). |
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| Authors: | CHEN Xu-Dong HUANG Xin-Hua |
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| Abstract: | The absorption spectroscopy of cyclopentalienyl-cumene iron hexafluorophosphate (Irgacure 261)in four solvents has been studied, the influence of irradiation on Irgacure 261 has been observed. The results show that the initiator can form complexes with acetonitrile and propylene oxide, The kinetics of photolysis of iron-arene complex has been determined,the photolysis reaction of initiator is the first order reaction, the rate constant of photolysis reaction is 0.391 min-1. |
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| Keywords: | Iron-arene complex Photoinitiator Absorption spectroscopy Photolysis |
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