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无机/有机杂化IPN的合成与表征
引用本文:王静媛,秦东奇,奚春宇,于晓强,李玉玮.无机/有机杂化IPN的合成与表征[J].高等学校化学学报,1998,19(8):1352-1354.
作者姓名:王静媛  秦东奇  奚春宇  于晓强  李玉玮
作者单位:吉林大学化学系,长春,130023
摘    要:随着互穿聚合物网络(IPN)的发展[1],出现了无机/有机杂化IPN[2],调整两组分或多组分互穿程度控制材料的结构、形态与性能,可使材料具有较宽的适用范围[3].此类材料具有高模量、高韧性,易成型加工,同时由于某些功能材料的掺杂,使其能应用于光学、...

关 键 词:分子筛13X  聚甲基丙烯酸  丁酯  杂化  IPN  PBMA

Synthesis and Characterization of Hybrid Inorganic/Organic Interpenetrating Polymer Networks
WANG Jing-Yuan,QIN Dong-Qi,XI Chun-Yu,YU Xiao-Qiang,LI Yu-Wei.Synthesis and Characterization of Hybrid Inorganic/Organic Interpenetrating Polymer Networks[J].Chemical Research In Chinese Universities,1998,19(8):1352-1354.
Authors:WANG Jing-Yuan  QIN Dong-Qi  XI Chun-Yu  YU Xiao-Qiang  LI Yu-Wei
Institution:WANG Jing Yuan *,QIN Dong Qi,XI Chun Yu,YU Xiao Qiang,LI Yu Wei
Abstract:A hybrid inorganic/organic interpenetrating polymer networks of a three dimensional network structure zeolite 13X and crosslinked or linear polybutylmethacrylate was prepared in this paper. By changing the content of crosslinker and the composition ratio, the size of zeolite channels and the crosslinking density were controlled. The results of DSC, SEM, TBA and mechanical properties show that zeolite 13X is an inorganic skeleton and some organic PBMA run through it, which makes the whole inorganic/organic IPN material not only have the rigidity of inorganic substance but also have the toughness of organic substance. At the same time it improves the thermal stability of organic material.
Keywords:Zeolite 13X  Poly(butyl methacrylate)  Hybrid inorganic/organic IPN  
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