| 新的铁盐体系催化合成聚乙炔 |
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| 引用本文： | 王征,吴健,乔亦男,王幼文,沈之荃.新的铁盐体系催化合成聚乙炔[J].高等学校化学学报,1988,9(1):67. |
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| 作者姓名： | 王征 吴健 乔亦男 王幼文 沈之荃 |
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| 作者单位： | 浙江大学化学系 |
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| 摘 要： | 本文发现并研究了三种乙炔定向聚合的新催化剂--环烷酸和膦酸酯铁盐与三烷基铝组成的配位络合催化剂.对所得的聚乙炔进行了IR、ESR、X-射线衍射、SEM、TEM、电阻率及元素分析等表征。结果表明,新催化剂具有聚合活性高,定向性好,可直接成膜等特点。同时发现Fe(P507)3催化所得聚乙炔有单晶衍射特征。此外,对聚乙炔膜的电化学及电池性能也进行了研究。
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| 收稿时间： | 1986-07-05 |
Synthesis of Cis-Polyacetylene with New Catalysts Consisting of Ferric Phosphates and Naphthenate |
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| Wang-Zheng,Wu Jian. Qiao-Yinan,Wang Youwen,Shen Zhiquan.Synthesis of Cis-Polyacetylene with New Catalysts Consisting of Ferric Phosphates and Naphthenate[J].Chemical Research In Chinese Universities,1988,9(1):67. |
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| Authors: | Wang-Zheng Wu Jian Qiao-Yinan Wang Youwen Shen Zhiquan |
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| Institution: | Department of Chemistry, Zhejiang University, Hangzhou |
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| Abstract: | The high cis-polyacetylene filmis with metallic appearance were synthesized by new coordination catalysts composed of Fe(naph), or Fe(P204)3 or Fe(P507)3 and aluminum trialkyl at room temperature.The resultant polyacetylene was charac-terized by IR, ESR, X-ray diffraction, SEM, TEM, electrical resistivity measurement and elemental analysis. The higher activity of polymerization and direct forming films of polyacetylene having rich cis-content were obtained with these catalysts.The single crystal and spot diagram from electron diffraction of polyaCetyl-ene prepared with the Fe(P507)3 system were found. Electrochemistry and batteryof polyacetylene were studied too. |
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