| 笼状双环磷酸酯类化合物的合成与生物活性研究 |
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| 引用本文： | 邵瑞链,王水平.笼状双环磷酸酯类化合物的合成与生物活性研究[J].高等学校化学学报,1991,12(8):1063-1065. |
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| 作者姓名： | 邵瑞链 王水平 |
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| 作者单位： | 南开大学元素有机化学研究所，解放军南昌陆军学院理化教研室，北京情报研究所 南昌 330029 |
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| 摘 要： | 近年来,科学家们相继合成出高度对称结构的双环磷酸酯笼状化合物,并研究了它们的生物活性,这类化合物具有良好的杀虫抗菌活性,且有独特的活性机理,在医药、农药、纤维、树脂及石油工业中已得到了广泛应用,本文采用季戊四醇和苯乙腈为起始原料,以下列反应步骤设计合成了8个新型笼状双环磷酸酯衍生物I,1′-硫(氧)代-2′,6′,7′-三三氧杂-1′-磷杂双环(2,2,2)辛烷基-4′-甲基]-4-烷基-4-苯基-4-氰基丁酸酯:
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| 关 键 词： | 双环 磷酸酯 笼状 生物活性 合成 |
Studies on Synthesis and Biological Activity of Caged Bicyclophosphate Compounds |
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| Shao Rui-lian.Studies on Synthesis and Biological Activity of Caged Bicyclophosphate Compounds[J].Chemical Research In Chinese Universities,1991,12(8):1063-1065. |
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| Authors: | Shao Rui-lian |
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| Abstract: | The study on the synthesis and biological activity of caged bicyclophosphate derivatives is one of the active fields in organophosphorus chemistry. Eight novel compounds with the general formula as ( I ) have been synthesized. Their structures were established by elemental analysis, 1R, 'H NMR and MS, Some of I showed a fungicidal activities. |
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| Keywords: | Caged bicyclophosphate Synthesis Biological activity |
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