| 钒氧酞菁分子沉积自组膜电极的组装及其对肼的电催化研究 |
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| 引用本文： | 孙长青,刘国晶,张鸿安.钒氧酞菁分子沉积自组膜电极的组装及其对肼的电催化研究[J].高等学校化学学报,1998,19(3):382-384. |
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| 作者姓名： | 孙长青 刘国晶 张鸿安 |
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| 作者单位： | 1. 吉林大学化学系, 长春, 130023;
2. 中国计量学院精细化工系, 杭州, 310012 |
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| 基金项目： | 中国科学院长春应用化学研究所电分析化学开放研究实验室资助 |
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| 摘 要： | 由于单层修饰电极具有组装有序、定向、密集、完好及可在分子水平上控制电极表面的微结构等特点，因此它特别适于电化学基础理论研究和应用［１～３］．但由于含有巯基的可用于单层组装的化合物，常用的功能尾端仅仅限于羧基、氨基和羟基几种，大大限制了该类单层电极的应...
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| 关 键 词： | 分子沉积技术 自组膜 钒氧酞菁 肼 |
| 收稿时间： | 1997-03-19 |
Fabrication of a Self-assembling Film Electrode Containing Vanadium-oxygen Phthalocyanine and Its Electrocatalytic Oxidation for Hydrazine |
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| SUN Chang-Qing,LIU Guo-Jing,ZHANG Hong-An.Fabrication of a Self-assembling Film Electrode Containing Vanadium-oxygen Phthalocyanine and Its Electrocatalytic Oxidation for Hydrazine[J].Chemical Research In Chinese Universities,1998,19(3):382-384. |
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| Authors: | SUN Chang-Qing LIU Guo-Jing ZHANG Hong-An |
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| Institution: | 1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Department of Fine Chemistry Research, China Institute of Metrology, Hangzhou, 310012 |
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| Abstract: | A monolayer containing vanadium oxygen phthalocyanine on the surface of 2 dimethylaminoethanethiol modified gold electrode was achieved based on electrostatic interaction.The electrode exhibits a high catalytic activity toward the electrooxidation of hydrazine. The method is very useful in other fabrication of functional molecules. |
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| Keywords: | Molecular deposition technique Self assembling film Vanadium oxygen phthalocyanine Hytrazine |
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