| 含腈基的电活性聚芳醚酮的合成与表征 |
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| 引用本文： | 姚雷,晁单明,刘新才,李智亮,王策.含腈基的电活性聚芳醚酮的合成与表征[J].高等学校化学学报,2010,31(6):1078-1080. |
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| 作者姓名： | 姚雷 晁单明 刘新才 李智亮 王策 |
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| 作者单位： | 吉林大学麦克德尔米德实验室, 长春 130012 |
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| 基金项目： | 国家自然科学基金，国家"八六三"计划项目 |
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| 摘 要： | 本文首先合成出含苯胺链段的双氟单体, 通过亲核取代反应, 采用三元共聚的方式, 制得了一种溶解性较好并有一定机械强度的新型电活性聚芳醚酮材料.
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| 关 键 词： | 电活性 氧化偶联 有机可溶性 高介电常数 |
| 收稿时间： | 2010-03-17 |
Synthesis and Characterization of New Electroactive Polyaryletherketone Containing Benzonitrile Structure |
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| YAO Lei,CHAO Dan-Ming,LIU Xin-Cai,LI Zhi-Liang,WANG Ce.Synthesis and Characterization of New Electroactive Polyaryletherketone Containing Benzonitrile Structure[J].Chemical Research In Chinese Universities,2010,31(6):1078-1080. |
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| Authors: | YAO Lei CHAO Dan-Ming LIU Xin-Cai LI Zhi-Liang WANG Ce |
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| Institution: | Alan G. MacDiarmid Institude, Jilin Univercity, Changchun 130012, China |
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| Abstract: | A new electroactive polyaryletherketone containing benzonitrile(EPEEK-CN) was synthesized from 2,6-difluorobenzonitrile,p-benzenediol and difluoromonomer containing phenyl-capped aniline tetramer segment,via ternary polycondensation.The obtained EPEEK-CN shows certain extent solubility in organic solvents,and its film casted from DMAc solution exhibits interesting electrical,mechanical and dielectric properties. |
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| Keywords: | Electroactivity Oxidative coupling Organosoluble High dielectric constant |
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