| 含手性双环胍的氨基酸受体的合成 |
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| 引用本文： | 何卫江.含手性双环胍的氨基酸受体的合成[J].高等学校化学学报,1997,18(11):1800-1803. |
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| 作者姓名： | 何卫江 |
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| 作者单位： | 南京大学化学系!南京，210093(何卫江，陆国元，胡宏纹)，马德里Autónoma大学化学系(JavierdeMendoza)，马德里Antónoma大学化学系(PilarPrados) |
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| 基金项目： | 国家自然科学基金!29472048 |
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| 摘 要： | 报道含有手性双环胍，氮杂冠醚及萘甲酰基３个分子识别点的芳香族氨基酸人工受体的合成。
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| 关 键 词： | 受体 氨基酸受体 分子识别 手性 双环胍 合成 |
Synthesis of an Receptor Containing Chiral Bicyclic Guanidine for Amino Acids |
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| HE Wei-Jiang, LU Guo-Yuan, HU Hong-Wen.Synthesis of an Receptor Containing Chiral Bicyclic Guanidine for Amino Acids[J].Chemical Research In Chinese Universities,1997,18(11):1800-1803. |
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| Authors: | HE Wei-Jiang LU Guo-Yuan HU Hong-Wen |
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| Abstract: | An artificial receptor 1 for aromatic amino acids was prepared from a chiralbicycllc guanidine salt 2 by means of a new procedures. The deprotecting silylethers 2 and 4were selectively achieved in solutions of CH3COOH-THF-H2O and HF-Pyridine respectively.Thus the receptor 1 was readily obtained upon reaction of the monosubstituted naphthoylester 5 with bromoacetic acid and then mono-azacrown ether. The total yield in five steps was40.5%. |
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| Keywords: | Receptor Amino acid Molecular recognition Synthesis |
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