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猴头菌寡糖的分离及其结构确定
引用本文:姜瑞芝,王颖,陈英红,高阳,黄恩喜,高其品.猴头菌寡糖的分离及其结构确定[J].高等学校化学学报,2007,28(7):1313-1315.
作者姓名:姜瑞芝  王颖  陈英红  高阳  黄恩喜  高其品
作者单位:1. 吉林省中医中药研究院,长春,130021
2. 吉林大学生命科学学院,长春,130023
3. 长春中医药大学研发中心,长春,130061
基金项目:国家科技部振兴东北老工业基地专项基金
摘    要:报道了从猴头菌浸膏中分离出猴头菌二糖和三糖, 并确定了其化学结构.

关 键 词:猴头菌浸膏  寡糖  电喷雾多级串联质谱
文章编号:0251-0790(2007)07-1313-03
收稿时间:2006-09-11
修稿时间:2006-09-11

Separation and Structural Identification of Hericium Erinaceur Oligosaccharide
JIANG Rui-Zhi,WANG Ying,CHEN Ying-Hong,GAO Yang,HUANG En-Xi,GAO Qi-Pin.Separation and Structural Identification of Hericium Erinaceur Oligosaccharide[J].Chemical Research In Chinese Universities,2007,28(7):1313-1315.
Authors:JIANG Rui-Zhi  WANG Ying  CHEN Ying-Hong  GAO Yang  HUANG En-Xi  GAO Qi-Pin
Institution:1. Academy of Chinese Medicine and Material Medical of Jilin Province, Changchun 130021, China; 2. School of Life Science, Jilin University, Changchun 130023, China; 3. Chinese Medicine and Material Medical University of Changchun, Centre of Study and Development, Changchun 130062, China
Abstract:It has been reported that the polysaccharide is the main active constituent of Hericium erinaceur.A series of oligosaccharide(mixtures of disaccharide and heptasaccharide of Hericium erinaceur) were separated from Hericium erinaceur by empty-fibrin filtration.Disaccharide and trisaccharide were purified via HPLC with NH2 column.Component sugars and glycosidic linkage ways were analysed via GC and GC-MS.Electrospray ionization tandem mass spectrometry(MSn) was used for the oligosaccharides structure study and the result shows that the disaccharide has two kind of structural styles and trisaccharide has one kind of structural style.
Keywords:Hericium erinaceur  Oligosaccharide  Electrospray ionization tandem mass spectrometry
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