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高灵敏度二氧化硫光纤传感器的研究
引用本文:许汉英,王柯敏,王大宁,李庆才.高灵敏度二氧化硫光纤传感器的研究[J].高等学校化学学报,1998,19(9):1401-1404.
作者姓名:许汉英  王柯敏  王大宁  李庆才
作者单位:1. 吉林进出口商品检验局, 长春, 130062; 2. 湖南大学化学化工学院, 长沙, 410082
基金项目:中华人民共和国进出口商品检验局科研基金
摘    要:以奎宁为荧光试剂,通过改变传感液膜的组成及采用非稳态测量法,研制成功高灵敏度的二氧化硫光纤传感器,该传感器的线性响应范围为3.1×10-7~7.8×10-5mol/L,检测限达1.6×10-7mol/L.研究了内充液中NaHSO3浓度、内充液层厚度对该光纤传感器动态响应信号的影响,用该传感器测定了葡萄酒中游离二氧化硫的含量,结果令人满意.

关 键 词:光纤传感器  二氧化硫  动态测定  
收稿时间:1997-12-31

Studies on a Fiber Optical Sensor for Sulfur Dioxide with a High Sensitivity
XU Han-Ying,WANG Ke-Min,WANG Da-Ning,LI Qing-Cai.Studies on a Fiber Optical Sensor for Sulfur Dioxide with a High Sensitivity[J].Chemical Research In Chinese Universities,1998,19(9):1401-1404.
Authors:XU Han-Ying  WANG Ke-Min  WANG Da-Ning  LI Qing-Cai
Institution:1. Jilin Import and Export Commodities Inspection Bureau, Changchun, 130062; 2. College of Chemical and Engineering, Hunan University, Changsha, 410082
Abstract:The present paper decribes a fiber optical sensor with a high sensitivity to determine sulfur dioxide. In order to improve the sensitivity, a non-steady state approach was adopted and the sensor response was recorded after the reaction being proceeded for 1 or 2 min. Effects of NaHSO3 concentration and thickness of sensing layer of liquid on the sensor response were investigated. Agood linearity in a wide concentration range of sulfur dioxide, 3.1×10-7 ~7.8×10-5 mol/L, was displayed. The detection limit was 1.6×10-7 mol/L. Using the sensor to determine the amounts of SO2 in the wine, the results were in good agreement with the results obtained by the standard method.
Keywords:Fiber optical sensor  Sulfur dioxide    Kinetic measurement  
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