| 5,10,15,20-四(对氯苯基)卟啉羟基稀土配合物的光谱研究 |
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| 引用本文： | 贾慧颖,徐蔚青,齐明辉,刘国发,李小灵,赵冰.5,10,15,20-四(对氯苯基)卟啉羟基稀土配合物的光谱研究[J].高等学校化学学报,2004,25(2):338-341. |
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| 作者姓名： | 贾慧颖 徐蔚青 齐明辉 刘国发 李小灵 赵冰 |
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| 作者单位： | 吉林大学超分子结构与材料教育部重点实验室,长春,130023;吉林大学化学学院,长春,130023 |
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| 基金项目： | 国家自然科学基金 (批准号 :2 0 173 0 19,2 0 2 73 0 2 2 ,2 9975 0 11)资助 |
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| 摘 要： | 研究了四(对氯苯基)卟啉及其羟基稀土配合物的紫外-可见光谱、红外光谱和拉曼光谱,对主要谱带进行了经验归属,讨论了中心离子对紫外光谱和共振拉曼光谱结构敏感带频率的影响.
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| 关 键 词： | 卟啉 紫外-可见光谱 红外光谱 共振拉曼光谱 |
| 文章编号： | 0251-0790(2004)02-0338-04 |
| 收稿时间： | 2003-05-17 |
Spectral Study of 5,10,15,20-Tetra( p -Chlorophenyl) Porphyrin Lanthanide Complexes |
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| JIA Hui-Ying,XU Wei-Qing{},QI Ming-Hui,LIU Guo-Fa,LI Xiao-Ling,ZHAO Bing.Spectral Study of 5,10,15,20-Tetra( p -Chlorophenyl) Porphyrin Lanthanide Complexes[J].Chemical Research In Chinese Universities,2004,25(2):338-341. |
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| Authors: | JIA Hui-Ying XU Wei-Qing{} QI Ming-Hui LIU Guo-Fa LI Xiao-Ling ZHAO Bing |
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| Institution: | JIA Hui-Ying+1,XU Wei-Qing+{1*},QI Ming-Hui+2,LIU Guo-Fa+2,LI Xiao-Ling+1,ZHAO Bing+1 |
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| Abstract: | The UV-Vis spectra, Infrared spectra and resonance Raman spectra of tetra(para-chlorophenyl)porphyrin and its coordination compounds LnT(%p%-Cl)PPOH(Ln: Tb, Lu, Er, Gd) were measured and investigated respectively. In UV-Vis spectra the effect of rare earth ions were discussed. Metal sensitive bands in IR spectra were found, and the effect of metal ion size on the marker bands frequencies in resonance Raman spectra was also discussed. |
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| Keywords: | Porphyrin UV-Vis spectra Infrared spectra Resonance Raman spectra |
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