| 气相C60与甲苯,氯化苄和对二甲苯反应研究 |
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| 引用本文： | 郭兴华,张法义.气相C60与甲苯,氯化苄和对二甲苯反应研究[J].高等学校化学学报,1993,14(4):563-565. |
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| 作者姓名： | 郭兴华 张法义 |
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| 作者单位： | 中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，南开大学化学系 长春 130022，长春 130022，长春 130022，长春 130022 |
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| 摘 要： | 在质谱离子源内,气相C_(60)分别与甲苯、氯化苄、对二甲苯产生的主要碎片离子及自由基反应,生成了C_(60)的多种气相衍生物离子,表明气相下C_(60)具有很活泼的化学性质。
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| 关 键 词： | 碳60 气相 离子分子反应 甲苯 |
A Study of the Reaction of C_(50) with Toluene, Benzyl Chloride and p-Xylene in Gas Phase |
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| GUO Xing-Hua,LIU Zi-Yang,SONG Feng-Rui,LIU Shu-Ying.A Study of the Reaction of C_(50) with Toluene, Benzyl Chloride and p-Xylene in Gas Phase[J].Chemical Research In Chinese Universities,1993,14(4):563-565. |
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| Authors: | GUO Xing-Hua LIU Zi-Yang SONG Feng-Rui LIU Shu-Ying |
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| Abstract: | In the ion source of mass spectrometer, the gas-phase C60 reacted with the ion or radical fragments of toluene, benzyl chloride and p-xylene and a series of derivative ions were formed in the gas phase. This indicates the gas-phase C80 has active chemical properties. Among them C60C7H7]+ and C60C6H5]+ are the predominant adduct ions. The C7H7+ ions are the mixture of tropylium, benzyl or tolyl ions in the gas phase, therefore the adduct ions C60C7H7]+ have four possible structures. |
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| Keywords: | Buckminsterfullerene Gas-phase ion-molecule reaction Toluene Benzyl chloride p-Xylene |
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