| 一种新型含萘聚醚酰亚胺的合成与表征 |
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| 引用本文： | 李鹏,陈春海,王冬佶,周宏伟,赵晓刚,党国栋.一种新型含萘聚醚酰亚胺的合成与表征[J].高等学校化学学报,2010,31(1):212-214. |
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| 作者姓名： | 李鹏 陈春海 王冬佶 周宏伟 赵晓刚 党国栋 |
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| 作者单位： | 吉林大学麦克德尔米德实验室,长春,130012 |
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| 基金项目： | 国家“九七三”计划项目(批准号:2010CB631100);;吉林省杰出青年基金资助 |
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| 摘 要： | 本文合成了一种新型含萘酰亚胺六元环结构的双氯单体BCNPI, 然后将其与双酚A双钠盐在环丁砜中高温缩聚, 得到一种新型含萘聚醚酰亚胺, 并对其基本性能进行表征.
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| 关 键 词： | 聚醚酰亚胺 萘酰亚胺 双氯单体 高温缩聚反应 |
| 收稿时间： | 2009-09-17 |
Synthesis and Characterization of Novel Polyetherimide Contained Naphthalene Structure |
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| LI Peng,CHEN Chun-Hai,WANG Dong-Ji,ZHOU Hong-Wei,ZHAO Xiao-Gang,DANG Guo-Dong.Synthesis and Characterization of Novel Polyetherimide Contained Naphthalene Structure[J].Chemical Research In Chinese Universities,2010,31(1):212-214. |
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| Authors: | LI Peng CHEN Chun-Hai WANG Dong-Ji ZHOU Hong-Wei ZHAO Xiao-Gang DANG Guo-Dong |
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| Institution: | Alan G. MacDiarmid Institute;Jilin University;Changchun 130012;China |
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| Abstract: | A novel dichioro-monomer 4,4'-bis(N-'phenyl-4-chloro-1,8-naphthalimide) ether(BCNPI) was successfully prepared. We obtain novel polyethernaphthalimide(PENI) from BCNPI and Bisphenol A salt in the present of sulfolane. The polymer possess high molecular weight from test of intrinsic viscosity and high Tg from the differential scanning calorimetry. The polyetherimide exhibited excellent thermal and thermooxidative stabilities,and it has high modulus,strength and elongation from the test of the mechanical prop... |
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| Keywords: | Polyetherimide Naphthalimide Dichloro-monomer High-temperature polymerization |
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