| 新型卟啉化合物的合成及性质 |
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| 引用本文： | 侯军,周子彦,吴学,朱东霞,李鹏.新型卟啉化合物的合成及性质[J].高等学校化学学报,2007,28(8):1424-1427. |
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| 作者姓名： | 侯军 周子彦 吴学 朱东霞 李鹏 |
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| 作者单位： | 1. 延边大学长白山生物功能因子省部共建教育部重点实验室,延吉,133002
2. 东北师范大学化学学院功能材料化学研究所,长春,130024 |
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| 基金项目： | 吉林省科技发展计划
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高等学校博士学科点专项科研项目 |
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| 摘 要： | 利用微波反应和模板效应合成了带有苯乙烯撑单元的新型卟啉化合物和锌卟啉配合物. 通过 1H NMR, IR和MALDI-TOF-MS等技术对其结构进行了表征. 通过测定UV-Vis和PL对两种卟啉化合物光学性能进行了研究. 利用TGA和循环伏安法研究了锌卟啉配合物的热稳定性和电化学性质, 并以锌卟啉配合物作为掺杂剂利用蒸镀法制备了电致发光器件, EL谱发射峰位于556 nm.
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| 关 键 词： | 卟啉 紫外-可见吸收光谱 合成 发光性能 器件 |
| 文章编号： | 0251-0790（2007）08-1424-04 |
| 收稿时间： | 2006-12-25 |
| 修稿时间： | 2006-12-25 |
Synthesis and Properties of Novel Porphyrin |
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| HOU Jun,ZHOU Zi-Yan,WU Xue,ZHU Dong-Xia,LI Peng.Synthesis and Properties of Novel Porphyrin[J].Chemical Research In Chinese Universities,2007,28(8):1424-1427. |
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| Authors: | HOU Jun ZHOU Zi-Yan WU Xue ZHU Dong-Xia LI Peng |
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| Institution: | 1. Key Laboratory of Organism Functional Factors of the Changbai Mountain, Ministry of Edncation, Yanfi 133002, China; 2. Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China |
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| Abstract: | The preparation of a novel porphyrin derivative bearing oligo(p-phenylene) group and its zinc complex was reported,which involved a microwave irradiation and a synthesis based on the template effects,respectively.Both of the porphyrin derivative and its zinc complex were fully characterized through IR,NMR and MALDI-TOF-MS.Optical properties(UV-Vis and fluorescence) was also studied for both compounds according to the spectra analysis,respectively.For zinc complex the thermal stabilities and electrochemistry were studied by TGA and CV.Further fabrication with the zinc complex as a dopant resulted in an electroluminescent device emission at 556 nm |
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| Keywords: | Porphyrin UV-Vis spectrum Synthesis Luminescent property Device |
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