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聚醚醚酮酮等温结晶动力学的研究
引用本文:陈艳,王军佐.聚醚醚酮酮等温结晶动力学的研究[J].高等学校化学学报,1995,16(2):322-324.
作者姓名:陈艳  王军佐
作者单位:吉林大学化学系,中国科学院化学研究所
摘    要:聚醚醚酮酮等温结晶动力学的研究陈艳,王军佐,曹俊奎,那辉,吴忠文(吉林大学化学系,长春,130023)关键词聚醚醚酮酮,等温结晶动力学,差示扫描量热法聚醚醚酮酮(PEEKK)是在聚醚醚酮(PEEK)基础上开发成功的一种耐热高分子材料。它保持了PEEK...

关 键 词:聚醚醚酮酮  等温  结晶动力学  差示扫描量热法

Studies on Isothermal Crystallization Kinetics of Poly(ether ether ketone ketone)
CHEN Yan,WANG Jun-Zuo,CAOJun-Kui,NA Hui,WU Zhong-Wen.Studies on Isothermal Crystallization Kinetics of Poly(ether ether ketone ketone)[J].Chemical Research In Chinese Universities,1995,16(2):322-324.
Authors:CHEN Yan  WANG Jun-Zuo  CAOJun-Kui  NA Hui  WU Zhong-Wen
Abstract:A study has been made for the crystallization behaviour of poly(ether ether ketone ketone) by DSC which was used to monitor the crystallization process from the melt and rubbery state.The Avrami equation was used to analyze the isothermal crystallization kinetics of PEEKK.The Avrami constant n is about 2 for the crystallization process from the melt and 1.5 from the rubbery state.The activation energies for PEEKK are 953.7 kJ/mol for crystallization from the melt and 932.6kJ/mol for crystallization from the rubbery state.The kinetic parameter kg is 851.5K
Keywords:Poly(ether ether ketone ketone)  Isothermal crystallization kinetics  Differential scanning calorimeter  
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