| n级反应的热动力学对比进度法 |
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| 引用本文： | 刘劲松,曾宪诚.n级反应的热动力学对比进度法[J].高等学校化学学报,1992,13(11):1466-1468. |
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| 作者姓名： | 刘劲松 曾宪诚 |
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| 作者单位： | 四川大学化学系 成都610064
(刘劲松，曾宪诚)，四川大学化学系 成都610064(邓郁) |
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| 摘 要： | 在化学反应的热动力学研究中,根据一次实验的热谱曲线来确定一个未知反应的级数,是一项很有理论和实际意义的工作.本文建立了n级反应的热动力学对比进度法.应用此法可判定反应级数和计算速率常数,并用实验及文献数据验证了本文方法的正确性.
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| 关 键 词： | n级反应 对比进度法 热动力学 |
Reduced Extent Method for Thermokinetics of n-Order Reactions |
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| LIU Jing-Song,ZENG Xian-Cheng,DENG Yu.Reduced Extent Method for Thermokinetics of n-Order Reactions[J].Chemical Research In Chinese Universities,1992,13(11):1466-1468. |
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| Authors: | LIU Jing-Song ZENG Xian-Cheng DENG Yu |
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| Abstract: | A reduced extent method for thermokinetics of n-order reactions is proposed,which is used for calculating the rate constants and determining the orders of reactions.The applications of the method are given,whose results are in agreement with those in literatures.And therefore,the method for thermokinetics of n-order reactions is believed to be correct. |
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| Keywords: | n-Order reaction Reduced extent method Thermokinetics Calorimetry |
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