| [In2(HPO3)4]·(NH3CH2CH2NH3)的水热合成与晶体结构 |
| |
| 引用本文： | 刘成站,朱广山,方千荣,薛铭,孙福兴,裘式纶.[In2(HPO3)4]·(NH3CH2CH2NH3)的水热合成与晶体结构[J].高等学校化学学报,2007,28(9):1637-1639. |
| |
| 作者姓名： | 刘成站 朱广山 方千荣 薛铭 孙福兴 裘式纶 |
| |
| 作者单位： | 1. 吉林大学无机合成与制备化学国家重点实验室,长春,130012;东北师范大学化学学院,长春,130024
2. 吉林大学无机合成与制备化学国家重点实验室,长春,130012 |
| |
| 摘 要： | 用乙二胺作模板剂在水热条件下合成出一个新的三维开放骨架结构的亚磷酸铟In2(HPO3)4]·(NH3CH2CH2NH3)(1), 并对其晶体结构进行了测定和表征.
|
| 关 键 词： | 水热合成 晶体结构 乙二胺 亚磷酸铟 |
| 文章编号： | 0251-0790（2007）09-1637-03 |
| 收稿时间： | 2006-12-27 |
| 修稿时间： | 2006-12-27 |
Hydrothermal Synthesis and Crystal Structure of [In2(HPO3)4]·(NH3CH2CH2NH3) |
| |
| LIU Cheng-Zhan,ZHU Guang-Shan,FANG Qiang-Rong,XUE Ming,SUN Fu-Xing,QIU Shi-Lun.Hydrothermal Synthesis and Crystal Structure of [In2(HPO3)4]·(NH3CH2CH2NH3)[J].Chemical Research In Chinese Universities,2007,28(9):1637-1639. |
| |
| Authors: | LIU Cheng-Zhan ZHU Guang-Shan FANG Qiang-Rong XUE Ming SUN Fu-Xing QIU Shi-Lun |
| |
| Institution: | 1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China; 2. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China |
| |
| Abstract: | A new three-dimensional indium phosphite, In2(HPO3)4]·(NH3CH2CH2NH3), was prepared under hydrothermal conditions via using ethylenediamine as a template. Its structure was solved by singlecrys-tal X-ray diffraction. The compound crystallizes in a monoclinic system, space group P2/n, with cell parameters a=0.91405(5) nm, b=0.91984(5) nm, c=0.96120(5) nm, β=115.9950(10)°, V=0.72640(7) nm3, Z=2, R1=0.0249, wR2=0.0650, GOF=1.044. The inorganic topological structure is built up from the vertex linking of InO6 octahedral and HPO3 pyramidal tetrahedral units, forming eight-membered ring channels along the 506] direction. The diprontonated ethylenediamine molecules are entrapped in eight-membered ring channels. |
| |
| Keywords: | Hydrothermal synthesis Crystal structure Ethylenediamine Indium phosphite |
| 本文献已被 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
