| PLLA-PEG共聚物的非等温结晶行为 |
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| 引用本文： | 任杰,桂宝珠,任天斌,杨军,顾明浩.PLLA-PEG共聚物的非等温结晶行为[J].高等学校化学学报,2007,28(10):2006-2009. |
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| 作者姓名： | 任杰 桂宝珠 任天斌 杨军 顾明浩 |
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| 作者单位： | 同济大学先进土木工程材料教育部重点实验室,上海,200092 |
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| 基金项目： | 国家高技术研究发展计划(863计划)
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教育部跨世纪优秀人才培养计划
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上海市科委科技攻关纳米专项基金 |
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| 摘 要： | 采用熔融共聚法制备PLLA-PEG嵌段共聚物, 用WAXD和DSC方法研究其结晶行为, 并用Avrami方程的Jeziorny修正分析了非等温结晶动力学行为. 结果表明, PLLA结晶明显, 而PEG结晶难以观察到, PEG的柔性能促进PLLA结晶. PEG分子量的增加和投料量的增加都能使得结晶温度升高, 结晶度增大, 结晶速度加快.
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| 关 键 词： | 聚乳酸 聚乙二醇 直接熔融缩聚 非等温结晶 |
| 文章编号： | 0251-0790（2007）10-2006-04 |
| 收稿时间： | 2007-03-30 |
| 修稿时间： | 2007-03-30 |
Non-isothermal Crystallization Behavior of PLLA-PEG Copolymer |
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| REN Jie,GUI Bao-Zhu,REN Tian-Bin,YANG Jun,GU Ming-Hao.Non-isothermal Crystallization Behavior of PLLA-PEG Copolymer[J].Chemical Research In Chinese Universities,2007,28(10):2006-2009. |
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| Authors: | REN Jie GUI Bao-Zhu REN Tian-Bin YANG Jun GU Ming-Hao |
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| Institution: | Key Laboratory of Advarwed Civil Engineering Materials, Ministry of Education, Tongii University, Shanghai 200092, China |
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| Abstract: | Poly(L-lactic acid)-poly(ethylene glycol) was copolymerized with direct melt copolymerization, and its crystallization was studied via WAXD and DSC. Via using Avrami equation modified by Jeziorny, the crystallization kinetics under a non-isothermal condition was analyzed. The crystallization of PLLA was obvious, while the PEG's could not observed. But the flexibility of PEG promoted PLLA's crystallization. And the crystalline temperature, velocity and crystallinity of PLLA-PEG increased with the increase of molecular weight of PEG and the feed weight ratio. |
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| Keywords: | Poly(lactic acid) Poly(ethylene glycol) Direct melt condensation polymerization Non-isothermal crystallization |
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