| Keggin结构阳离子[AlO4Al12(OH)24(H2O)12]7+与杂多阴离子构筑的新型无机纳米簇凝胶 |
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| 引用本文： | 彭革,胡长文,陈立东,王恩波.Keggin结构阳离子[AlO4Al12(OH)24(H2O)12]7+与杂多阴离子构筑的新型无机纳米簇凝胶[J].高等学校化学学报,2001,22(10):1629-1631. |
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| 作者姓名： | 彭革 胡长文 陈立东 王恩波 |
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| 作者单位： | 东北师范大学化学学院,多酸化学研究所, |
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| 基金项目： | 国家自然科学基金，教育部高校骨干教师资助计划，20071007，，， |
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| 摘 要： | 多金属氧酸盐（Polyoxometalates POMs）化学已成为材料科学、医学、催化及光化学等诸多领域的活跃研究课题1～5]。
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| 关 键 词： | Keggin结构阳离子 杂多阴离子 合成 结构表征 无机纳米簇凝胶 同多铝酸阳离子 |
| 文章编号： | 0251-0790(2001)10-1629-03 |
Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO4Al12(OH)24(H2O)12]7+ and Heteropolyoxometalates |
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| PENG Ge,HU Chang\|Wen\,CHEN Li\|Dong,WANG En\|Bo.Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO4Al12(OH)24(H2O)12]7+ and Heteropolyoxometalates[J].Chemical Research In Chinese Universities,2001,22(10):1629-1631. |
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| Authors: | PENG Ge HU Chang\|Wen\ CHEN Li\|Dong WANG En\|Bo |
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| Institution: | PENG Ge,HU Chang\|Wen\+*,CHEN Li\|Dong,WANG En\|Bo |
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| Abstract: | The novel class of inorganic nanoclusters, \{\AlO\-4Al\-\{12\}(OH)\-\{24\}(H\-2O)\-\{12\}\]\}\{\SiW\-\{11\}O\-\{39\}CoCl\]\}\511H\-2O, \{\AlO\-4Al\-\{12\}(OH)\-\{24\}(H\-2O)\-\{12\}\]\}\{\P\-2W\-\{18\}O\-\{62\}\]\}Cl\533H\-2O and \{\AlO\-4Al\-\{12\}(OH)\-\{24\}(H\-2O)\-\{12\}\]\}\-2\NaP\-5W\-\{30\}O\-\{110\}\]\524H\-2O, consisting of Keggin cations and heteropolyoxometalates, has been synthesized and characterized by ICP, IR and NMR. It is proved that the intrinsic identities of Keggin cation and heteropolyanions of the clusters are preserved within the gels. |
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| Keywords: | Keggin\|type cation Heteropolyoxometalates Synthesis Structural characterization Gel |
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