| 云南重楼中的新甾体皂苷 |
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| 引用本文： | 徐暾海,毛晓霞,徐雅娟,解生旭,赵洪峰,司云珊,韩冬,李彧,牛建昭,徐东铭.云南重楼中的新甾体皂苷[J].高等学校化学学报,2007,28(12):2303-2306. |
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| 作者姓名： | 徐暾海 毛晓霞 徐雅娟 解生旭 赵洪峰 司云珊 韩冬 李彧 牛建昭 徐东铭 |
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| 作者单位： | 1. 北京中医药大学中药学院中药化学系,北京,100102
2. 吉林省中医中药研究院中药化学实验室,长春,130021 |
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| 基金项目： | 教育部长江学者和创新团队发展计划
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国际科技合作计划项目 |
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| 摘 要： | 从云南重楼Paris polyphylla Sm. var. yunnanensis(France. )Hand.-Mazz.的干燥根茎中分离鉴定了4个甾体皂苷(1~4), 其中化合物1是新化合物, 采用波谱技术鉴定其结构为24-O-β-D-吡喃半乳糖基-(23S,24S)-螺甾-5, 25(27)-二烯-1β,3β,23,24-四醇-1-O-β-D-吡喃木糖基(1→6)-β-D-吡喃葡萄糖基(1→3)α-L-吡喃鼠李糖基(1→2)]-β-D-吡喃葡萄糖苷.
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| 关 键 词： | 重楼 活性成分 甾体皂苷 |
| 文章编号： | 0251-0790（2007）12-2303-04 |
| 收稿时间： | 2007-05-09 |
| 修稿时间： | 2007年5月9日 |
New Steroidal Saponin from Paris polyphylla Sm. var. yunnanensis (France.) Hand. -Mazz. |
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| XU Tun-Hai,MA Xiao-Xia,XU Ya-Juan,XIE Sheng-Xu,ZHAO Hong-Feng,SI Yun-Shan,HAN Dong,LI Yu,NIU Jian-Zhao,XU Dong-Ming.New Steroidal Saponin from Paris polyphylla Sm. var. yunnanensis (France.) Hand. -Mazz.[J].Chemical Research In Chinese Universities,2007,28(12):2303-2306. |
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| Authors: | XU Tun-Hai MA Xiao-Xia XU Ya-Juan XIE Sheng-Xu ZHAO Hong-Feng SI Yun-Shan HAN Dong LI Yu NIU Jian-Zhao XU Dong-Ming |
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| Institution: | Department of Chinese Medicine Chemistry, School of Traditional Chinese Medicine, Beijing University of Chinese Medicine, Beijing 100102, China;;Laboratory of Chinese Medicine Chemistry, Academy of Traditional Chinese Medicine and Material Medica of Jilin Province, Changchun 130021, China |
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| Abstract: | Traditional Chinese Medicine “zhonglou”(Paris polyphylla) is the important medicine used to treat traumatism. A new steroidal saponin, together with four known steroidal saponins, was isolated from the rhizoma of Paris polyphylla. The structure of the new steroidal saponin, named Paripolyside A was elucidated as 24-O-β-D-galactopylanosyl-(23S,24S)-spirosta-5, 25(27)-diene-1β,3β,23, 24-tetrol-1-O-β-D-xylopylanosyl(1→6)-β-D-glucopyranosyl(1→3)α-L-rhamnopyranosyl(1→2)]-β-D-glucopyranoside mainly by using 1D, 2D NMR techniques, ESI-MS analysis as well as chemical methods. |
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| Keywords: | Paris polyphylla Active composition Steroidal saponin |
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