| C_（60）的胺加成反应和电喷雾电离质谱（ESI－MS）检测 |
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| 引用本文： | 魏先文,吴鸣飞,张诚,戚苓,徐正,曹亚澄,周克瑜.C_（60）的胺加成反应和电喷雾电离质谱（ESI－MS）检测[J].高等学校化学学报,1996(10). |
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| 作者姓名： | 魏先文 吴鸣飞 张诚 戚苓 徐正 曹亚澄 周克瑜 |
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| 作者单位： | 南京大学配位化学研究所，中国科学院南京土壤研究所 |
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| 摘 要： | 报道了Ｃ６０与１，３－丙二胺和Ｎ，Ｎ－二甲基－１，３－丙二胺的加合反应，反应产物未经预先离子化处理直接用ＥＳＬ－ＭＳ进行检测。由于反应产物从甲苯溶液中析出，避免了生成多胺基加合物，产物以单加成物为主。当加合反应在空气氛下进行时，有加合氧的产物Ｃ６０Ｏｎ（ＮＨ２—ＣＨ２ＣＨ２ＣＨ２ＮＲ２）ｍ（Ｒ＝Ｈ，ＣＨ３）存在。实验发现：Ｎ，Ｎ－二甲基－１，３－丙二胺比１，３－丙二胺更容易与Ｃ６０发生多胺基加成和氧加成反应。通过控制反应条件可制备Ｃ６０二胺的单加成产物。
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| 关 键 词： | C_（60）化学，胺加合物，电喷雾电离质谱 |
Addition Recation of Buckminsterfullerent with Amines and Electrospray Ionization Mass Spectrometry Determination of Reaction Products |
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| WEI Xian-Wen,WU Ming-Fei,ZHANG Cheng,QI Ling,XU Zheng.Addition Recation of Buckminsterfullerent with Amines and Electrospray Ionization Mass Spectrometry Determination of Reaction Products[J].Chemical Research In Chinese Universities,1996(10). |
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| Authors: | WEI Xian-Wen WU Ming-Fei ZHANG Cheng QI Ling XU Zheng |
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| Abstract: | The addition reactions of C60 with trimethylenediamine and 3-dimethyl-aminopropylamine were reported.The reaction products were determined directly by ESI-MS without pre-ionization.The reaction product precipitated from toluene,which prevented from polyaminates and led the mono-diamine adduct as a main product.Addition to main product there are some C60ON(NH2CH)2CH2CH2NR2)m(R=H,CH3) when the reaction runs at open air.The mono-diamine adduct may be gotten with control reaction condition. |
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| Keywords: | C_(60) chemistry Aminates ESI-MS |
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