| 苯乙烯/N-苯基马来酰亚胺共聚物分子量测定和模型 |
| |
| 引用本文： | 单国荣,翁志学,黄志明,潘祖仁.苯乙烯/N-苯基马来酰亚胺共聚物分子量测定和模型[J].高等学校化学学报,2000,21(9):1473-1476. |
| |
| 作者姓名： | 单国荣 翁志学 黄志明 潘祖仁 |
| |
| 作者单位： | 浙江大学化工系高分子科学与工程研究所,杭州,310027 |
| |
| 基金项目： | 教育部博士学科点专项基金!(批准号 :953350 4 )资助 |
| |
| 摘 要： | 从内聚能的角度建立了含共聚组成、序列不均匀性的共聚物分子量及分布理论，导出其计算式。将凝胶渗透色谱（ＧＰＣ）与紫外吸光谱（ＵＶ）和示差折光仪（ＤＲ）串接，测定苯乙烯（Ｓｔ）／Ｎ－苯基马来酰亚胺（ＰＭＩ）共聚物的分子量。根据Ｓｔ／ＰＭＩ共聚合原理，对Ｓｔ－ＰＭＩ共聚物的分子量进行模型化，该模型能较好地预测引发剂、单体配比、转化率对共聚物分子量的影响。
|
| 关 键 词： | 苯乙烯 N－苯基马来酰亚胺 共聚物 分子量测定 |
Measurement and Model of Molecular Weight for Styrene/N-Phenylmaleimide Copolymer |
| |
| SHAN Guo-Rong,WENG Zhi-Xue,HUANG Zhi-Ming,PAN Zu-Ren.Measurement and Model of Molecular Weight for Styrene/N-Phenylmaleimide Copolymer[J].Chemical Research In Chinese Universities,2000,21(9):1473-1476. |
| |
| Authors: | SHAN Guo-Rong WENG Zhi-Xue HUANG Zhi-Ming PAN Zu-Ren |
| |
| Institution: | SHAN Guo-Rong *,WENG Zhi-Xue,HUANG Zhi-Ming,PAN Zu-Ren |
| |
| Abstract: | The molecular weight theory and calculation equation of copolymer were set up after consideration with the influence of composition and sequence distribution. The molecular weight for St/PMI copolymer was investigated by means of GPC connected with DR and UV detectors. From the mechanism of St/PMI copolymerization, a model of molecular weight for St-PMI copolymer was proposed to predicate the effects of initiator concentration, feed fraction and conversion on the molecular weight of St-PMI copolymer. The predicted results coincided with the experimental data. |
| |
| Keywords: | Styrene N-Phenylmaleimide Molecular weight of copolymer |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
