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不同孔径的介孔碳分子筛对VB12的吸附性质研究
引用本文:郭卓,朱广山,辛明红,高波,裘式纶.不同孔径的介孔碳分子筛对VB12的吸附性质研究[J].高等学校化学学报,2006,27(1):9-12.
作者姓名:郭卓  朱广山  辛明红  高波  裘式纶
作者单位:吉林大学无机合成与制备化学国家重点实验室,长春,130012
摘    要:摘要利用SBA-15为模板, 在不同温度下合成了孔径大小在3.7(CMK-3-100)和6-3 nm(CMK-3-150)之间的介孔碳, 以其作为吸附剂, 研究了它们在水溶液中对VB12的吸附作用. 结果表明, CMK-3-130与CMK-3-100和CMK-3-150相比, 表现出对VB12最大的吸附能力(吸附能力为412.5 mg/g), 这是因为它有比较高的有序结构和比较大的孔容.

关 键 词:SBA-15  介孔碳  吸附性质  VB12
文章编号:0251-0790(2006)01-0009-04
收稿时间:01 5 2005 12:00AM
修稿时间:2005-01-05

Adsorption Behavior of VB12 on Mesoporous Carbon Molecular Sieves with Different Pore Diameters
GUO Zhuo,ZHU Guang-Shan,XIN Ming-Hong,GAO Bo,QIU Shi-Lun.Adsorption Behavior of VB12 on Mesoporous Carbon Molecular Sieves with Different Pore Diameters[J].Chemical Research In Chinese Universities,2006,27(1):9-12.
Authors:GUO Zhuo  ZHU Guang-Shan  XIN Ming-Hong  GAO Bo  QIU Shi-Lun
Institution:State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
Abstract:The CMK-3-130 exhibits the largest adsorption capacity than CMK-3-100 and CMK-3-150.Mesoporous carbon sieves were prepared from SBA-15 materials at different temperatures.This allows the synthesis of mesoporous carbons sieves with pore dismeters in the range from 3.7 nm(CMK-3-100) to 6.3 nm(CMK-3-150).The mesoporous carbons sieves were studied in the adsorption of VB_12 from water solutions.The maximal adsorption capacity of 412.5 mg/g was found for CMK-3-130,which is probably a consequence of its highly ordered mesostructures and larger pore.
Keywords:SBA-15  Mesoporous carbon  Adsorption behavior  VB_12  
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