| 醚的初始暗氧化反应机理的研究 |
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| 引用本文： | 朱军民,曹维孝,冯新德.醚的初始暗氧化反应机理的研究[J].高等学校化学学报,1998,19(7):1181-1183. |
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| 作者姓名： | 朱军民 曹维孝 冯新德 |
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| 作者单位： | 北京大学化学与分子工程学院, 北京, 100871 |
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| 摘 要： | 有机化合物的空气氧化是一个历史悠久的研究课题。早在1851年Schonbein1]就注意到醚在空气中会被氧化产生过氧化物。本世纪初,Clover和Milas分析了醚的空气氧化产物,并且对醚的氧化机理,进行了研究。
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| 关 键 词： | 接触电荷转移复合物 紫外吸收光谱 暗氧化反应机理 |
| 收稿时间： | 1997-06-20 |
Studies on the Mechanism of the Initial Dark Oxidation of Ethers |
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| ZHU Jun-Min,CAO Wei-Xiao,FENG Xin-De.Studies on the Mechanism of the Initial Dark Oxidation of Ethers[J].Chemical Research In Chinese Universities,1998,19(7):1181-1183. |
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| Authors: | ZHU Jun-Min CAO Wei-Xiao FENG Xin-De |
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| Institution: | College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 |
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| Abstract: | The contact charge transfer (CCT) complexes of isopropyl ether, phenyl isopropyl ether and benzyl isopropyl ether with O 2 were measured. It was found that the oxygenative position of isopropyl ether is different from that of phenyl isopropyl ether and benzyl isopropyl ether due to benzene ring in their structures. In the former the oxygenative position is at the etheroxy bond while in the latter at the benzene ring. The mechanism of the initial dark oxidation of ether was proposed. |
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| Keywords: | Contact charge transfer(CCT) complex Ultraviolet absorption spectrum Dark oxidation mechanism |
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