首页 | 本学科首页   官方微博 | 高级检索  
     检索      

三维银配位聚合物[Ag3(IN)2(CF3COO)]的水热合成与晶体结构
引用本文:田戈,袁宏明,陈岩,李光华,冯守华.三维银配位聚合物[Ag3(IN)2(CF3COO)]的水热合成与晶体结构[J].高等学校化学学报,2006,27(11):2045-2047.
作者姓名:田戈  袁宏明  陈岩  李光华  冯守华
作者单位:吉林大学无机合成与制备化学国家重点实验室,化学学院,长春,130012
摘    要:本文在水热条件下, 通过4-氰基吡啶发生原位水解得到异烟酸, 将其与AgCF3CO2作用合成了新型银配位聚合物, 并通过元素分析和X射线单晶衍射分析等手段对其结构进行了表征.

关 键 词:水热合成  晶体结构  银配位聚合物
文章编号:0251-0790(2006)11-2045-03
收稿时间:02 27 2006 12:00AM
修稿时间:2006-02-27

Hydrothermal Synthesis and Crystal Structure of a Novel Three-dimensional Silver Coordination Polymer[Ag3(IN)2(CF3COO)]
TIAN Ge,YUAN Hong-Ming,CHEN Yan,LI Guang-Hua,FENG Shou-Hua.Hydrothermal Synthesis and Crystal Structure of a Novel Three-dimensional Silver Coordination Polymer[Ag3(IN)2(CF3COO)][J].Chemical Research In Chinese Universities,2006,27(11):2045-2047.
Authors:TIAN Ge  YUAN Hong-Ming  CHEN Yan  LI Guang-Hua  FENG Shou-Hua
Institution:State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Abstract:A three-dimensional silver coordination polymer,(Ag_(3)(IN)_(2)(CF_(3)COO))](IN=Isonicotinic acid),was synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction.The compound crystallizes in the triclinic space group P-1,with unit cell parameters a=0.918 48(5) nm,b=1.013 92(6) nm,c=1.067 05(6) nm,Z=2,R_(1)=0.036 5,wR_(2)=0.095 5.The Ag centers are bridged by the IN and CF_(3)CO_(2) ligands to form three-dimensional structure.There are strong Ag-Ag bond interaction in the framework.
Keywords:Hydrothermal synthesis  Crystal structure  Silver coordination polymer
本文献已被 CNKI 维普 万方数据 等数据库收录!
点击此处可从《高等学校化学学报》浏览原始摘要信息
点击此处可从《高等学校化学学报》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号