| Ni催化剂上一氧化碳加氢反应机理研究 |
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| 引用本文： | 胡云行,关玉德.Ni催化剂上一氧化碳加氢反应机理研究[J].高等学校化学学报,1995,16(8):1289-1291. |
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| 作者姓名： | 胡云行 关玉德 |
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| 作者单位： | 厦门大学化学系，中国科学院山西煤炭化学研究所 |
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| 摘 要： | Ｎｉ催化剂上一氧化碳加氢反应机理研究胡云行，万惠霖，关玉德，林恒生（厦门大学化学系，固体表面物理化学国家重点实验室，厦门，３６１００５）（中国科学院山西煤炭化学研究所，太原）关键词脉冲法，一氧化碳，加氢，反应机理自本世纪初报道了一氧化碳加氢生成甲烷以...
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| 关 键 词： | 一氧化碳 反应机理 加氢反应 镍催化剂 |
Studies on Mechanism of CO Hydrogenation over Ni/Al_2O_3 |
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| HU Yun-Hang,WAN Hui-Lin.Studies on Mechanism of CO Hydrogenation over Ni/Al_2O_3[J].Chemical Research In Chinese Universities,1995,16(8):1289-1291. |
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| Authors: | HU Yun-Hang WAN Hui-Lin |
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| Abstract: | The mechanism of CO hydrogenation to CH4 over Ni catalysts was studied by response method of differential pulses and BOC-MP method.It was suggested that the dissociation of CO under the promotion of hydrogen was favorable over Ni(111),whereas the direct dissociation of CO was favorable over Ni(100).Moreover,it was shown that hydrogenation of surface C to CH species was the rate-determining step. |
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| Keywords: | Pulse method CO Hydrogenation Reaction mechanism |
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